Study of the possibility of synthesis of stable submicron tin dioxide and its application for sorption extraction Pb(II), Cd(II)

Keywords: adsorption, heavy metals, submicron particles, the stabilizer of particle size

Abstract

The possibility of chemical synthesis and sorption properties of submicron tin dioxide with a particle size of 3-5 microns with respect to Cu(II), Pb(II), and Cd(II) ions are investigated. The possibility of using glycerol as a stabilizer of the particle size of the resulting tin dioxide is shown. It is established that the sorption of the studied metal ions by particles of submicron tin dioxide is described by the Langmuir model. Optimization of the sorption conditions allowed us to achieve a high sorption activity of submicron tin dioxide with respect to the specified ions Pb(II) 97%, Cd (II) 77%. The high sorption efficiency of the obtained submicron tin dioxide hydrosol was revealed in comparison with the corresponding literature data.

References

Davydov S. L., Tarasov V. I. (2002). Heavy metals as supertoxicants of the XXI century. M.: RUDN. (in Russ.)

Ilyasova R. R., Saptarov Yu. N., Knyazeva O. A., Sapatrova L. M., Kogina E. N. (2018). Determination of heavy metal ions by atomic absorption spectrometry in blood plasma during intoxication with copper-zinc pyrite ore. Bulletin of the Bashkir University. 23(2), 316‒322. https://doi.org/10.33184/bulletin-bsu-2018.2.11. (in Russ.)

Ilyasova R. R., Saparova L. M., Kogina E. N., Sattarov Yu. N., Nasibullin A. D. Karimova G. I. Yurasov, A. Y. (2019). Determination of heavy metals in mineralizate biological objects by the method of atomic absorption spectrometry. Bulletin of the Bashkir University. 24(1), 76‒80. https://doi.org/10.33184/bulletin-bsu-2019.1.13 (in Russ.)

Moore J., Ramamoorthy S. (1987). Heavy metals in natural waters. M.: World.

Requirements for the quality of drinking water (SanPiN 2.1.4.1074-01). http://water2you.ru/n-docs/pdk_sanpin/ (accessed 26.02.2021) (in Russ.)

Bespamyatnov G. P., Krotov Yu. A. (1985). Maximum permissible concentrations of chemicals in the environment. Guide. L.: Chemistry. (in Russ.)

Dolina L. F. (2008). Modern equipment and technologies for wastewater treatment from heavy metal salts. Dnipropetrovsk: The Continent. (in Russ.)

Borilo L. P., Petrovskaya T. S., Lyutova E. S. (2014). Synthesis and properties of thin films based on the phases of the SiO2–P2O5–CaO system. Inorganic materials. 8, 874‒880. https://doi.org/10.7868/s0002337x14080053 (in Russ.)

Zima T. (2017). Synthesis and research of three-dimensional flower-like structures based on tin dioxide. Inorganic materials. 12, 1311. https://doi.org/10.7868/s0002337x17120090 (in Russ.)

Ryaguzov A. P., Nemkaeva R. R., Huseynov N. R. (2018). Influence of tin synthesis conditions and nanoparticles on the structure and properties of composite thin films a-C: H. Physics and engineering of semiconductors. 10, 1207–1259. https://doi.org/10.21883/ftp.2018.10.46463.8785 (in Russ.)

Maksimova N. K., Biryukov A. A., Sevastyanov Yu. A., Chernikov E. V. (2020). Structure and properties of hydrogen sulfide sensors based on thin tin dioxide films. Journal of Applied Chemistry. 93(3), 414‒424. https://doi.org/10.31857/s0044461820030147.

Lidin R. A. Chemical properties of inorganic substances. (2000). M.: Chemistry.

Rovenskiy B. V. (2008). Laboratory workshop on general and biophysical chemistry. Moscow: The science.

PNDF 16.1:2:2.2:2.3.78-2013. Method of measuring the mass fraction of mobile forms of metals: copper, zinc, lead, cadmium, manganese, nickel, cobalt, chromium in samples of soils, soils, bottom sediments, sediments, and wastewater by atomic absorption spectrometry (2013). http://standartgost.ru/g/%D0%9F%D0%9D%D0%94_%D0%A4_16.1:2:2.2:2. 3.78-2013 (accessed 26.02.2021) (in Russ.)

Stumm W., Huang C.P., Jenkins S.R. (1970) Specific chemical interactions affecting the stability of dispersed systems. Croat. Chim. Acta. 42, 223‒244.

Kaplaushenko A. G., Pryakhin O. R., Varinsky B. O., Yurchenko I. O., Shcherbak M. O., Samelyuk Yu. G., Kucheryaviy Yu. M., Gulina E. S. (2016). Physical and chemical properties of dispersive systems. Zaporozhye: ZSMU. (in Russ.)

Grover V.A., Hu J.A, Shipley H.J. (2012). Adsorption and desorption of bivalent metals to hematite nanoparticles Environ. Toxicol. Chem. 31, 86‒92. https://doi.org/10.1002/etc.712

Shipley H.J., Engates R.E., Grover V.A. (2013). Removal of Pb(II), Cd(II), Cu(II), and Zn(II) by hematite nanoparticles: effect of sorbent concentration, pH, temperature, and exhaustion. Environ. Sci, Pollut. Res. 20, 1727‒1736.

All-Saad K.A., Amr M.A., Hadi D.T. (2012). Arab. J. Nuclear Sci. a. Applications. 45(2), 335‒346.

Published
2021-06-15
How to Cite
Ilyasova, R. R., Masslimov, I. A., & Mustafin, A. G. (2021). Study of the possibility of synthesis of stable submicron tin dioxide and its application for sorption extraction Pb(II), Cd(II). Chemical Safety Science, 5(1), 81 - 94. https://doi.org/10.25514/CHS.2021.1.19005
Section
Technologies for elimination of chemical hazards