Special aspects of the purification of dicyclohexyl-18-crown-6 through the preparation of crystalline stoichiometric complexes with HN-acid organic molecules
Abstract
A technological procedure for the synthesis and purification of dicyclohexyl-18-crown-6 (DCG18C6) by the method of liquid-phase catalytic hydrogenation of DB18C6 on a ruthenium catalyst in 50% isopropanol at elevated pressure and temperature is presented. An efficient method for the isolation of a mixture of isomers A and B of DCH18C6 and their separation is proposed. It is promising to use DB18C6 as a component in various composites for efficient removal of Sr2+ in media with high acidity.
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