Study of Sorption Mechanisms of Heavy Metal Ions in their Individual and Combined Presence in Model Solutions
Abstract
Adsorption treatment as an effective method of cleaning industrial wastewater from heavy metal ions is considered. Experimental studies on absorption of copper(II), iron(III), chromium(VI), aluminum(III) ions from model solutions on organic materials - peat and sawdust were carried out. Experiments were also carried out in the joint presence of copper and iron ions in the model solution, as they are often found in wastewater, in a ratio of 1:1. The optimum method of spectrographic determination in the combined presence of the above ions was also selected. Based on the experimental studies, adsorption isotherms were constructed and the analysis of the obtained isotherms using different models, the approximation coefficient was chosen as the criterion of consistency. It is shown that according to the proposed models it is impossible to describe the adsorption process by one of the models for one sorbent, the sorption of each heavy metal ion is described by its own model
References
Ignatov M.D. Analysis of the State and Organization of Work on SDC in the Russian Federation (2021). NovaInfo, 126, 21‒22. (in Russ.).
Dashti A., Amirkhani F., Jokar M. et al. (2021). Insights into the estimation of heavy metals ions sorption from aqueous environment onto natural zeolite. Int. J. Environ. Sci. Technol., 18, 1773–1784. https://doi.org/10.1007/s13762-020-02912-9.
Rahim A.R., Iswarya, Johari K., Shehzad N., Saman N., & Mat H. (2021). Conversion of coconut waste into cost effective adsorbent for Cu(II) and Ni(II) removal from aqueous solutions. Environmental Engineering Research, 26(4), 200250. https://doi.org/10.4491/eer.2020.250
Gebretsadik H., Gebrekidan A., & Demlie L. (2020). Removal of heavy metals from aqueous solutions using Eucalyptus Camaldulensis: An alternate low cost adsorbent. Cogent Chemistry, 6:1. https://doi.org/10.1080/23312009.2020.1720892.
Zakharyan S.V. (2020). Study of sorption methods for extracting rhenium from washing acid and development of a technology for obtaining high-purity ammonium perrhenate (Ph.D. dissertation). Yekaterinburg: UrFU, (in Russ.).
Dubrovskay O.G., Kulagin V.A., Kurilina T.A., & Li Feng-Chen. (2017). Application of modified sorption material for efficient wastewater treatment of galvanic production. J. Sib. Fed. Univ. Eng. technol., 10(5), 621-630. https://doi.org/10.17516/1999-494X2017-10-5-621-630.
Perelygin Yu. P., Bikunova M.V., Laskov N.N., & Shein A.I. (2017). Calculation of optimal values of the hydrogen index in the deposition of heavy metal ions in wastewater of industrial enterprises. Regional Architecture and Construction, 4(33), 111-115. (in Russ.).
Kulakov A.A., Kuznetsova Y.N., & Denisova A.E. (2017) On wastewater purification from heavy metal ions using electroplating method. Proceedings of the XVII International Scientific Conference “Chemistry and Environmental Engineering” Kazan: KNITU-KAI, 26-28. (in Russ.).
Proleichik A.Y., Gaponenkov I.A., & Fedorova O.A. (2018). Extraction of heavy metal ions from inorganic wastewater. Ecology and Industry of Russia, 22(3), 35‒39. https://doi.org/10.18412/1816-0395-2018-3-35-39. (in Russ.).
Galimova R.Z., Shaikhiev I.G., & Nguyen T.K.T. (2020). Adsorption of copper (II) ions on modified bark of Acacia auriculiformis. Environmental Chemistry, 29(4), 196‒200.
Pham Thanh Minh. (2019). Development of sorbents from non-traditional raw materials for wastewater treatment (Ph.D. dissertation). Belgorod: BSTU named after V.G. Shukhov, (in Russ.).
Pomazkina O.I. (2020). Purification of wastewater from ions of toxic metals using modified aluminosilicates (Ph.D. dissertation). Vladivostok: FEFU, (in Russ.).
Shakirova V.V., Sadomtseva O.S., Koshkin E.M., & Kozhina A.D. (2016). Study of sorption processes of some heavy metal ions on natural materials. Natural Sciences: Chemistry, 4(57), 118‒124. (in Russ.).
Laptedulche N.K., & Dremicheva E.S. (2014). Comparative assessment of the effectiveness of sorption treatment of wastewater from heavy metals. Water: chemistry and ecology, 12(78), 81‒87. (in Russ.).
Trang T.Y.D., & Zenitova L.A. (2021). Polymer composite material based on polyurethane and chitin - the sorbent of heavy metal ions. Bulletin of the University of Technology, 24(1), 26–31.
Shaburov EL, Derevyanko OV, Fedyukhin AV, Smyatskaya SA, & Politaeva NA (2019). Determination of calorific value of spent sorbents from residual biomass of Chlorella Sorokiniana and Lemna Minor bryoza. Proceedings of Higher Education Institutions. Problems of Energy, 21(3‒4), 113‒121. https://doi.org/10.30724/1998-9903-2019-21-3-4-113-121. (in Russ.).
Cheremisina O.V., Schenk J., Cheremisina E.A., & Ponomareva M.A. (2019). Thermodynamic model of ion-exchange processes as an example of cerium sorption from complex salt solutions. Proceedings of the Mining Institute, 237, 307‒316. https://doi.org/10.31897/PMI.2019.3.307. (in Russ.).
Dremicheva E.S. (2017) Studying the sorption kinetics on peat ions of iron(III) and copper(II) from wastewater. Moscow University Chemistry Bulletin, 72(4), 196–199. https://doi.org/10.3103/S0027131417040034.
Çalımlı, M.H., Demirbaş, Ö., Aygün, A. et al. (2019) Equilibrium, Kinetics and Thermodynamics of Bovine Serum Albumin from Carbon Based Materials Obtained from Food Wastes. BioNanoSci. 9, 692–701. https://doi.org/10.1007/s12668-019-00633-z.
Gunko A.A. (2008). Investigations of copper mines XVII-XIX c.c. in Tatarstan. Caves, 31, 74‒90. (in Russ.).
Kats E.M., Nikashina V.A., & Bychkova Y.V. (2013). Sorption of heavy metals Ni, Cd, Cr, Zn, Cu from surface water on natural and modified clinoptilolites. Sorption and chromatographic processes, 13(6), 808‒815. (in Russ.).
Dyganova R.Y., & Yumanova N.V. (2009). Promising use of brucite in the technologies of wastewater treatment of heavy metal ions at thermal power facilities. Proceedings of higher educational institutions. Problems of Power Engineering, 11‒12, 115‒122. (in Russ.).
Dremicheva E.S., & Laptev A.G. (2019). Modeling the process of sorption for the purification of waste water from petroleum products and heavy metals. Theoretical Foundations of Chemical Engineering, 53(3), 355–363. https://doi.org/10.1134/S0040579519030047.
Stroganova E.A. (2018). Mechanisms of Competitive Sorption of Germanium(IV) and Copper(II) Ions from Chloride Solutions with Anion Exchanger AN-31 (Ph.D. dissertation). Orenburg: OSU, (in Russ.).
Vernigora A.N., Volkova N.V., & Guskova E.N. (2017) Simultaneous spectrophotometric determination of copper (II) and iron (III) in the joint presence as complexes with sulfosalicylic acid. Bulletin of Penza State University, 2(17), 85‒91. (in Russ.).
Copyright (c) 2022 Elena S. Dremicheva
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
