Bioactive glassy systems of the SiO2-CaO-P2O5 type doped with zinc(II) and manganese(II) compounds: efficient synthesis and properties
Abstract
The results of a comparative assessment of the synthesis conditions, physicochemical characteristics, and bioactivity of glassy systems of the form 60SiO2 – (36–x)CaO – 4P2O5 – xZnO (x = 1, 3, 5% mol.), 70SiO2 – (26–x)CaO – 4P2O5 – xMnO (x = 0, 3, 5% mol.). It has been established that the sintering temperature for obtaining zinc- and manganese-containing powders is 700°C. It is found that amorphous properties are observed for all synthesized systems 60SiO235CaO4P2O51ZnO, 60SiO233CaO4P2O53ZnO, 60SiO231CaO4P2O55ZnO, 70SiO226CaO4P2O5, 70SiO223CaO4P2O53MnO, 70SiO221CaO4P2O55MnO. It is shown that zinc- and manganese-containing systems are bioglasses. With an increase in the content of ZnO and MnO(II), the bioactivity of the systems decreases. The most active formation of hydroxyapatite layers is observed for 70SiO226CaO4P2O5 and 70SiO223CaO4P2O53MnO. Zinc-containing systems can be arranged according to bioactivity in the following order: 60SiO235CaO4P2O51ZnO > 60SiO233CaO4P2O53ZnO > 60SiO231CaO4P2O55ZnO. The results of studies of textural properties show that Zn(II) ions are vitreous network modifiers at 1÷3% mol., replacing calcium and silicon ions. The presence of phosphorus(V) oxide in the system prevents complete modification and destruction of the vitreous network with an increase in the content of Zn(II) ions up to 5% mol. The influence of MnO oxide additives on thermal properties has been established, which is expressed in a decrease in the phase transition temperature with an increase in the MnO content from 0 to 5% mol. The selection of starting materials and the scheme of the process were carried out using the principles of «green chemistry».
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