Radiation-chemical transformations of crude oil hydrocarbons from the Gunashli field in the Republic of Azerbaijan on the surface of nanoclay
Abstract
The features of the dynamics of the transformation of functional groups in crude oil are studied and the role of surface – intermadiate products in the dynamics of changes in the catalytical radiolysis process has been revealed. The influence of the role of active centers of clay minerals in the adsorption interaction has been studied. The structural-group composition of the transformed oil under the influence of gamma-quanta in the presence of sodium bentonite clay was studied by IR –spectroscopy. Interactions of clay nanoparticles with hydrocarbons can cause cooperative effects, thereby causing or preventing the formation of aromatic hydrocarbons. On the base of study physicochemical processes on the surface of nanoclay, new approaches can be developed for the metamorphism of natural oil. The informations about the properties and composition of crude oil during radiolysis in the presence of nanoclay can be used to establish its genesis, since a characteristic feature of catalysis is associated with the cyclic nature of the processes.
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