Prospects the development of purification methods of sludge-lignin deposits of JSC “Baikal Pulp Mill” with polymer electrolytes

  • Yaroslava N. Golubeva Federal State Budgetary Educational Institution of Higher Professional Education “MIREA – Russian Technological University”, Moscow, Russia
  • Tatiana A. Chebotareva Federal State Budgetary Educational Institution of Higher Professional Education “MIREA – Russian Technological University”, Moscow, Russia
  • Anastasiya A. Tokareva Federal State Budgetary Educational Institution of Higher Professional Education “MIREA – Russian Technological University”, Moscow, Russia https://orcid.org/0000-0002-7917-7698
  • Alexandr V. Krylov Federal State Budgetary Educational Institution of Higher Professional Education “MIREA – Russian Technological University”, Moscow, Russia https://orcid.org/0000-0003-1928-2346
  • Pavel V. Zheglaty Federal State Budgetary Educational Institution of Higher Professional Education “MIREA – Russian Technological University”, Moscow, Russia
DOI: https://doi.org/10.25514/CHS.2023.2.25004
Keywords: wastewater, surfactants, polyelectrolytes, coagulants, polydimethyldiallylammonium chloride,coagulation, flocculation, sludge water, inorganic salts.

Abstract

The work analyzes the sludge sediments of the filler cards of the Baikal Pulp Mill (BCC) for the content of metal salts accumulated both as a result of the production activities of the BCC and the discharge of ash waste from heating plants and household wastes. The dependence of the content of metal salts on the concentration of sulfur-containing compounds, the acidity of the medium and the content of hardness salts has been established. The effectiveness of the interaction of polymer coagulants/flocculants based on quaternary ammonium compounds (Q+X‒) with inorganic metal salts of composition 1:2 (MeX2) in a wide range of acidity from strongly alkaline to strongly acidic environments has been studied. It has been shown that, depending on the nature of the metal, predominantly double salts (Q+Cl‒)2·MeCl2 or complex compounds of the Q+2[MeCl4]‒2 type are formed in acidic chloride media; in the case of Cd salts, the formation of complex polyanions is possible. In alkaline media, the polyelectrolyte is strongly adsorbed on the surface of solid metal hydroxides and hydroxychlorides, which leads to the polymer effect of enlarging particle sizes via a bridging mechanism. The established type of interaction makes it possible to develop effective methods for purifying KN sludge from metal salts whose concentrations exceed the MPC values (Pb, Cd, Ni). using polyelectrolytes based on quaternary ammonium salts.

References

Monney I., Buamah R., Donkor E. A., Etuaful R., Nota H. K., & Ijzer H. (2019). Treating waste with waste: the potential of synthesized alum from bauxite waste for treating car wash wastewater for reuse. Environmental Science and Pollution Research, 26(13), 12755–12764. https://doi.org/10.1007/s11356-019-04730-0.

Chebykin E.P., Dambinov YU.A., & Suturin A.N. (2020). Multi-element analysis of above-sludge waters in the accumulation cells of baykalsk pulp and paper mill for territory remediation strategy choosing. Water and ecology: problems and solutions. 4(84), 67–80. https://doi.org/10.23968/2305-3488.2020.25.4.67-80.

Bogdanov A.V. (2009) Development of scientific and practical foundations of technologies for complex processing of sediment from sludge storage tanks (Doctoral dissertation). Irkutsk: Irkutsk State Technical University 2009. (in Russ.).

Suturin A. N. (2012). The Baikal ecosystem can be destroyed by man-made waste. Ecology and life, 2, 82–85 (in Russ).

Veit M.T., Novais G.V., Juchen P.T., Palácio S.M., Gonçalves G.C., & Zanette J.C. (2020). Automotive Wash Effluent Treatment Using Combined Process of Coagulation/Flocculation/Sedimentation–Adsorption. Water Air Soil Pollut, 231(10), 494(12). https://doi.org/10.1007/s11270-020-04862-x.

Komarovsky D.P., & Monyak T.M. (2016). Application of aluminum-containing coagulants for water treatment of the Western Dvina river. Bulletin of the Brest State Technical University. Series: Water management construction, thermal power engineering and geoecology, 2, 74–77 (In Russ.).

Novakov I. A., Radchenko F. S., & Papisov I. M. (2003) On the formation of polycomplexes based on polyacrylamide and aluminum salts. High molecular weight compounds. Series A, 45(8), 1340–1344.

Tokareva A.A., Krylov A.V., Bondareva A.M., Chebotareva T.A., & Zheglaty P.V. (2023) Integrated approaches to the treatment of complexly contaminated wastewater. Khimicheskaya bezopasnost’ = Chemical safety science. 7(1), 81–92. https://doi.org/10.25514/CHS.2023.1.24006.

Xin-Hui, Su C., Tow Teng T., Morad N., & Rafatullah M. (2016). Optimisation of the Coagulation-Flocculation of Reactive Dye Wastewater Using Novel Inorganic-Organic Hybrid Polymer. Iranica Journal of Energy and Environment, 7(1), 31−38. https://doi.org/10.5829/IDOSI.IJEE.2016.07.01.05.

Abujazar M., Karaagac S.U., & Bashir M. (2022). Recent advancement in the application of hybrid coagulants in coagulation-flocculation of wastewater: A review. Journal of Cleaner Production, 345, 131133. https://doi.org/10.1016/j.jclepro.2022.131133.

Shevchenko V.S., & Zakharov V.R. (2002). The experience of using flocculant VPK-402 in the practice of water treatment at water treatment plants. Omsk Scientific Bulletin. 18, 70−71. (in Russ.).

Brandt M.J., Johnson K. M., Elphinston A.J., & Ratnayaka D.D. (2017). Chapter 8 - Storage, Clarification and Chemical Treatment. Twort's Water Supply (Seventh Edition), 323−366. https://doi.org/10.1016/B978-0-08-100025-0.00008-9.

Tian B., Ge X., Pan G., Fan B., & Zhaokun L. (2006). Adsorption and flocculation behaviors of polydiallyldimethylammonium (PDADMA) salts: influence of counterion. International Journal of Mineral Processing, 79, 209−216. https://doi.org/10.1016/j.minpro.2005.11.012.

Jianfeng Y., Dongsheng W., Mingquan Y., Changqing Y., Min Y., & Xiaopeng G. (2007). Optimized Coagulation of High Alkalinity, Low Temperature and Particle Water: pH Adjustment and Polyelectrolytes as Coagulant Aids. Environmental Monitoring and Assessment, 131, 377–386. https://doi.org/10.1007/s10661-006-9483-3.

Mihai M., Dragan E. S., Schwar S., & Janke A. (2007). Dependency of Particle Sizes and Colloidal Stability of Polyelectrolyte Complex Dispersions on Polyanion Structure and Preparation Mode Investigated by Dynamic Light Scattering and Atomic Force Microscopy. Journal of Physical Chemistry B, 111, 8668−8675. https://doi.org/10.1021/jp071655q.

Kudaibergenov S.E., Tatykhanova G.S., Arinov B. Zh., Kozhakhmetov S.K., & Aseyev V.O. (2008). Hybrid inorganic-organic nano- and microcomposites based on silica sols and synthetic polyelectrolytes. Polymer Letters, 2(2), 101–110. https://doi.org/10.3144/expresspolymlett.2008.14.

Beltrán-Heredia J., & Sánchez-Martín J. (2009). Municipal wastewater treatment by modified tannin flocculant agent. Desalination, 249(1), 353–358. https://doi.org/10.1016/j.desal.2009.01.039.

Buchhammer Heide-Marie, Petzold G., & Lunkwitz K. (1999) Salt Effect on Formation and Properties of Interpolyelectrolyte Complexes and Their Interactions with Silica Particles. Langmuir, 15, 4306–4310. . https://doi.org/10.1021/la980992a.

Greenwood, N.N. & Earnshaw, A. (1984). Chemistry of elements. N.Y.: Pergamon Press.

Gusev I.M., Skripkin M.Yu., Spektor K., & Starova G.L. (2011) Solution-equilibrium of the solid phase in MgBr2-NR4Br-H2O systems at 25°C (R = Me, Et, Bu ) Journal of General Chemistry, 81(4), 623–627.https://doi.org/10.1134/S1070363211040013.

Gusev I.M., & Skripkin M.Yu. (2011) Formation of complex and double salts in MX2-NR4X-H2O systems [M = Cd(II), Cu(II), Co(II), Mg(II) ; X = Cl, Br; R = Me, Et, Bu] at 25°C. Russian Journal of Applied Chemistry, 84(1), 25–35.https://doi.org/10.1134/S1070427211010046.

Gusev I.M., Skripkin M.Yu., & Burkov K. (2010) Solution-solid phase equilibrium in the systems MBr2NR4 BrH2O (M = Cd, Cu, Co; R = Me, Et, Bu) at 25°C . Russian Journal of General Chemistry, 80(8), 1563–1567 https://doi.org/10.1134/S1070363210080049.

Kustov, A.V. (2014). Hydrophobic effects: Structural, thermodynamic, applied aspects. Achievements of recent years. M.: KRASAND(in Russ.).

Hlela F., Rheima A., Guerfelb T., & Guidaraa K. (2006) Synthesis, Calorimetric Study, Infrared Spectroscopy and Crystal Structure Investigation of β-[Tetraethyl-ammonium Tetramethylammonium Tetrachlorozincate(II)] [β]-[(C2H5) 4N][(CH3)4N]ZnCl4. Z. Naturforsch. 61b, 1002–1006. https://doi.org/10.1515/znb-2006-0812

Zolotov, Yu.A., Iofa, B.Z. & Chuchatin, L.K. (1973) Extraction of halide complex metals. M.: Science (in Russ.).

Filippova, N.A. (1975). Phase analysis of ores and products of their processing. M.: Chemistry (in Russ.).

Tripathi U. P. (1972) Synthesis and structural study of some new alkylammonium tetrachlorometallates (II) (Ph.D. dissertation). Montana State University.

Baes C.F., & Mesmer R.E. (1976). The hydrolysis of Cations. New York: Wiley. P. 89.

Richens, D. T. (1997) The Chemistry of Aqua Ions: Synthesis, Structure and Reactivity: A Tour Through the Periodic Table of the Elements. Wiley. P. 68.

Pesterfield, L.L. & Schweitzer, G.K. (2010) The Aqueous Chemistry of the Elements. Oxford University Press. P. 146. https://doi.org/10.1093/oso/9780195393354.001.0001

Published
2023-12-05
How to Cite
Golubeva, Y. N., Chebotareva, T. A., Tokareva, A. A., Krylov, A. V., & Zheglaty, P. V. (2023). Prospects the development of purification methods of sludge-lignin deposits of JSC “Baikal Pulp Mill” with polymer electrolytes. Chemical Safety Science, 7(2), 55–73. https://doi.org/10.25514/CHS.2023.2.25004
Issue
Vol 7 No 2 (2023)
Section
Technologies for elimination of chemical hazards

Copyright (c) 2023 Yaroslava N. Golubeva, Tatiana M. Chebotareva, Anastasiya A. Tokareva, Alexander V. Krylov, and Pavel V. Zheglaty

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